O-W-403-9 CH3ReO3/Cl-Al2O3: A Novel Highly Active and Stable Catalyst for Olefin Metathesis

Wednesday, June 17, 2015: 2:10 PM
403-405 (Lawrence Convention Center)
Alessandro Gallo1, Julia Rieb1, Regis M. Gauvin2, Mostafa Taoufik3, Laurent Delevoye2, Anthony Fong1, Baron Peters1 and Susannah L. Scott1, (1)University of California Santa Barbara, USA, (2)Universite Lille Nord de France, France, (3)Université Lyon 1, France.
CH3ReO3 (MTO) interacting with the surface of extensively chlorinated γ-Al2O3 is a highly active catalyst for olefin metathesis. Its activity, selectivity and stability exceed that of any other reported MTO-based catalyst as measured in propene metathesis, including MTO/SiO2-Al2O3 and MTO/ZnCl2/γ-Al2O3, and are far higher than MTO/γ-Al2O3.

Extended Abstracts:

See more of: Catalyst Design I
See more of: Catalyst Design and Synthesis
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