P-Mo-B-74 Palladium Nanoparticles on Zinc Oxide-Passivated Porous Carbon for Enhanced Performance in Lithium-Oxygen Batteries

Monday, June 15, 2015
Ballroom B (Lawrence Convention Center)
Mar Piernavieja Hermida1, Yu Lei1, Xiangyi Luo2,3, Tianpin Wu2, Jun Lu2, Jianguo Wen2, Dean Miller2, Zhigang Fang3 and Khalil Amine2, (1)University of Alabama - Huntsville, USA, (2)Argonne National Laboratory, USA, (3)University of Utah, USA.
This works examines a cathode architecture design for lithium-oxygen batteries to prevent the high discharge/charge overpotentials. The materials in this architecture, Pd/ZnO/C, are synthesized using atomic layer deposition. The results show a low charge overpotential and higher electrochemical catalytic activity than the Pd/Al2O3/C cathode architecture.