O-Th-A-2 Valorization of Vegetable Oils Via Metathesis Reactions: Cross- Metathesis of Methyl Oleate with 1-Hexene on Supported Hoveyda-Grubbs Catalysts

Thursday, June 18, 2015: 8:20 AM
Ballroom A (Lawrence Convention Center)
Carlos Apesteguia, Juan Zelin, Pablo Nieres and Andrés Trasarti, INCAPE, Argentina.
Cross-metathesis of fatty acid methyl esters (FAME) with lower olefins may form valuable intermediates in fine chemistry. This work shows that yields to cross-metathesis products of about 70% are obtained at 303K from the reaction between methyl oleate and 1-hexene on silica-supported Hoveyda-Grubbs complexes.


Extended Abstracts: