P-We-148 Hydrogenation of N-benzylideneaniline by a new ruthenium(II) complex derivated from 2-ferrocenyl-1,8-naphthyridine

Wednesday, June 8, 2011
Ontario Exhibit Hall (Detroit Marriott Hotel at the Renaissance Center )
Pedro Aguirre Sr., Departamento de Iniorgánica y Analítica, Universidad de Chile, Facultad de Ciencias Químicas y Farmacéuticas, Santiago de Chile, Chile
The cis,cis,cis-dicarbonyl-dichloro-bis (2-ferrocenyl - 1,8-naphthyridine) ruthenium(II)  showed to be an active catalyst in the hydrogenation of N-benzylideneaniline by hydrogen transfer. The compound exhibits high stability during the catalytic process and conversion values between 89-33% were found in 6 hours of reaction for a substrate/catalyst ratio of 200/1 and 400/1

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