P-We-146 Synthesis and characterizationof compounds of Pd(II) with Phosphorus-Nitrogen Ligand. Applicarion as Catalysts in Methoxycarbonylation of Olefin

Wednesday, June 8, 2011
Ontario Exhibit Hall (Detroit Marriott Hotel at the Renaissance Center )
Sergio A. Moya, Química de los Materiales, Universidad de Santiago de Chile, Facultad de Química y Biología, Santiago de Chile, Chile
The catalysts of the type Pd(PN)(PPh3)Cl]Cl appeared to be active  in the reaction of olefin hydroesterification . For these catalysts the reaction is favored by the presence of PPh3 and PN ligand. The cationic character of the first compounds allows a better interaction with substrates and p-toluene sulphonic acid.

Extended Abstracts: