P-Tu-148 Oxidation of cis-Cyclooctene on Heterogeneous Mn-tmtacn Catalysts

Tuesday, June 7, 2011
Ontario Exhibit Hall (Detroit Marriott Hotel at the Renaissance Center )
Kathryn R. Bjorkman, Department of Chemical and Biological Engineering, Northwestern University, Evanston, IL and Linda J. Broadbelt, Chemical and Biological Engineering, Northwestern University, Evanston, IL
Microkinetic modeling is used with experimental observations to elucidate the reaction mechanism of cis-cyclooctene oxidation with H2O2 on heterogeneous Mn-tmtacn catalysts, providing valuable information such as model-predicted data, reaction orders, and rate-determining steps for future catalyst development and optimization of the reaction conditions for tuning product selectivity.

Extended Abstracts:

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