Kinetic and Mechanistic Aspects of C5 Acid Ketonization into Green Diesel Fuel Components over Pd on Metal Oxides

Simakov, Andrey V.

Wednesday, June 17, 2015

Ballroom B (Lawrence Convention Center)

Irina L. Simakova, Boreskov Institute of Catalysis, Russia; Novosibirsk State University, Russia and Andrey V. Simakov, Universidad Nacional Autónoma de México, Centro de Nanociencias y Nanotecnología, Mexico.

Valeric acid decarboxylative ketonization to 5-nonanone followed by hydrodeoxygenation into n-nonane over Pd and Pt catalysts in H₂ atmosphere was studied. Both catalytic reactions were studied separately in order to be performed thereafter in a cascade mode over the best bifunctional catalyst, which turned out to be Pt(Pd)/M_xO_y.

Extended Abstracts:

24thNAM_Simakova_KetonizationF.pdf (284.4KB) - Extended Abstract

P-W-B-162 Kinetic and Mechanistic Aspects of C5 Acid Ketonization into Green Diesel Fuel Components over Pd on Metal Oxides