O-Tu-403-11 Olefin and Arene Hydrogenation By a Silica Supported Well-Defined Fe2+ Catalyst

Tuesday, June 16, 2015: 5:00 PM
403-405 (Lawrence Convention Center)
Bo Hu1,2, Andrew Getsoian1, Guanghui Zhang1, Jeffrey T. Miller1 and Adam S. Hock1,2, (1)Argonne National Laboratory, USA, (2)Illinois Institute of Technology, USA.
A silica supported three coordinate, single-site Fe2+ is prepared by grafting Fe[N(SiMe3)2]2 onto silica followed by H2 treatment at 250oC. The resulting surface Fe2+ not only exhibited room temperature (30oC) propene hydrogenation activity, but also can hydrogenate toluene under 150 psi H2 at 100oC.

Extended Abstracts:

See more of: Hydrogenation Catalysts I
See more of: Catalyst Design and Synthesis
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