Increasing Robustness of Grafted Ti-Calixarene Olefin Epoxidation Catalysts Via Surface Polymerization and Crosslinking

Guo, Yijun

Friday, June 19, 2015: 10:20 AM

403-405 (Lawrence Convention Center)

Yijun Guo, Andrew Solovyov and Alexander Katz, University of California Berkeley, USA.

We demonstrate a new surface polymerization that enables synthesis of a catalyst that is both highly active, due to the gentle nature of the surface polymerization, which does not block access to the site or plug micropores, as well as more hydrolytically stable.

Extended Abstracts:

Yijun Guo NACS 2015v3.pdf (167.7KB) - Extended Abstract

O-F-403-6 Increasing Robustness of Grafted Ti-Calixarene Olefin Epoxidation Catalysts Via Surface Polymerization and Crosslinking