P-Tu-B-148 Aminocarbonylation Reaction Using Palladium Catalysts Containing Quinolone-Phosphine Ligands

Tuesday, June 16, 2015
Ballroom B (Lawrence Convention Center)
Pedro Aguirre Sr.1, Braulio Aranda1, Gonzalo Valdebenito1 and Sergio A. Moya2, (1)Universidad de Chile, Facultad de Ciencias Químicas y Farmacéuticas, Chile, (2)Universidad de Santiago de Chile, Facultad de Química y Biología, Chile.
In this work we show the catalytic results of the aminocarbonylation of iodobenzene using Pd(II) complexes containing a series of new phosphorous-nitrogen ligands derivated from quinoline. This reaction yielded 99% average after 3 hours with all the studied ligands with a chemoselectivity towards ketocarboxamide formation.

Extended Abstracts: