Immobilization of Ru Complexes on Periodic Mesoporous Organosilica and Catalytic Application in Selective Alkane Oxidation

Hara, Kenji

Tuesday, June 16, 2015: 1:30 PM

403-405 (Lawrence Convention Center)

Kenji Hara^1,2, Nobuhiro Ishito¹, Yoshifumi Maegawa^2,3, Shinji Inagaki^2,3 and Atsushi Fukuoka¹, (1)Hokkaido University, Japan, (2)JST/ACT-C, Japan, (3)Toyota Central R&D Labs. Inc., Japan.

The periodic mesoporous organosilica bearing 2,2’-bipyridine unit was selected as a promising support for the immobilization of Run species. The present catalyst thus obtained exhibited extremely high selectivity in oxidation of tertiary C-H bonds of admantane by using inexpensive NaClO as oxidant as well as good reusability.

Extended Abstracts:

Abstract_NAM24_Hara_20141030.pdf (167.4KB) - Extended Abstract

O-Tu-403-14 Immobilization of Ru Complexes on Periodic Mesoporous Organosilica and Catalytic Application in Selective Alkane Oxidation