P-Mo-B-34 Olefin Synthesis from Syngas on MoS2/Al2O3 Catalysts Promoted with Different Alkali Metals and Metal Precursors

Monday, June 15, 2015
Ballroom B (Lawrence Convention Center)
Chang Liu, Mirella Virginie, Anne Griboval Constant and Andrei Khodakov, Université Lille 1-ENSCL-EC Lille, France.
The work identifies the most efficient alkali promoters and precursors for direct olefin synthesis from syngas on supported molybdenum sulfide catalysts. The presence of very strong basic sites is not favorable for carbon monoxide conversion. The selectivity to C2-4 olefins, methanol and higher alcohol is attributed to mixed alkali-Mo sulfides.

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