Low Temperature Oligomerization of 1-Butene over H-Ferrierite

Xu, Zhuoran

Thursday, June 18, 2015: 2:10 PM

301-303 (Lawrence Convention Center)

Zhuoran Xu¹, George W. Huber¹, Yong Tae Kim¹, Joseph Chada¹, Yomaira Pagan Torres², Devon Rosenfeld², Bill Winniford² and Eric Schmidt², (1)University of Wisconsin Madison, USA, (2)Dow Chemical Company, USA.

We report on the low temperatures (100-250 ^oC) oligomerization of 1-butene over H-Ferrierite. The catalyst activity and stability increase with increasing butene partial pressure, and with the addition of a hydrocarbon solvent. The olefins selectivity increases with decreasing reaction temperature. The products follow an Anderson Shulz Flory chain growth model.

Extended Abstracts:

Low temperature oligomerization of 1-butene over H-Ferrierite.pdf (46.9KB) - Extended Abstract

O-Th-301-12 Low Temperature Oligomerization of 1-Butene over H-Ferrierite