O-M-408-9 Pore Network Changes of Single Catalyst Particles Due to Metal Poisoning

Monday, June 15, 2015: 1:50 PM
408-410 (Lawrence Convention Center)
Florian Meirer1, Sam Kalirai1, Yijin Liu2, Joy Andrews2, Ulrike Boesenberg3, Matthias Alfeld3, Gerald Falkenberg3, Santosh Soparawalla4, Darius Morris2,4, Gerbrand Mesu4 and Bert M. Weckhuysen1, (1)Utrecht University, Netherlands, (2)Stanford University, USA, (3)Deutsches Elektronen-Synchrotron DESY, Germany, (4)Albemarle Corporation, USA.
Based X-ray nano-tomography data we developed an analytical approach evaluating changes in the macro-pore network of single FCC particles due to metal deposition. Our findings elucidate one critical factor of catalyst failure in this industrially important system. Furthermore, the developed method can be applied to various hierarchically complex porous materials.

Extended Abstracts: