O-M-408-11 Active Phase Distribution Changes within a Catalyst Particle during Fischer-Tropsch As Revealed By Multi-Scale Microscopy

Monday, June 15, 2015: 2:30 PM
408-410 (Lawrence Convention Center)
Korneel Cats1, Joy Andrews2, Odile Stéphan3, Katia March3, Chithra Karunakaran4, Florian Meirer1, Frank de Groot1 and Bert Weckhuysen1, (1)Utrecht University, Netherlands, (2)Stanford University, USA, (3)Université Paris Sud, France, (4)Canadian Light Source, Canada.
Three chemical imaging techniques with different spatial resolutions have been applied to investigate the deactivation of cobalt Fischer-Tropsch catalysts. We observe changes in the macro- and nano-distributions of cobalt in a single catalyst particle. Cobalt forms a more homogeneous macroscopic distribution, including a 1-2 nm cobalt layer around titanium oxide.

Extended Abstracts: