P-Tu-BRC-29 Densely Packed Monolayer of Rh-diisocynide on Gold Surface as Platforms for Highly Active and Selective Catalysis

Tuesday, June 4, 2013
Ballroom C (Galt House Hotel)
Kenji Hara1, Sachin Jagtap1, Yoshinori Kaji1, Wang Jae Chun2 and Atsushi Fukuoka1, (1)Hokkaido University, Japan, (2)International Christian University, .
Gold surface was modified with 4,4'-terphenylenediisocyanide to form a densely packed monolayer, which was utilized as a platform for high turnover and selective Rh-catalysis in 1,4-hydrogenation of α,β-unsaturated carbonyl compounds.

Extended Abstracts: