O-W-Seg-6 Structure Sensitivity Conferred By Decoration of Low-Coordination Sites: Pt Cluster Size Effects in CO Oxidation at Moderate Temperatures

Wednesday, June 5, 2013: 11:20 AM
Segell (Galt House Hotel)
Monica Garcia-Dieguez and Enrique Iglesia, University of California Berkeley, USA.
This work provides mechanistic interpretations of kinetic and isotopic data for CO oxidation on Pt at moderate temperatures (700-800 K) and describes the implications for observed effects of cluster size on turnover rates and a sensitivity to structure absent at lower or higher temperatures.

Extended Abstracts: