Characterization of Metal-organic Frameworks (MOFs) for Catalytic Applications by Combining Physical and Chemical Adsorption Techniques

Combining advanced physical and chemical adsorption techniques gives a clear picture of the pore structure and acidic sites in metal-organic framework (MOF) catalysts. Applicability of NH₃ chemisorption (static and dynamic) for assessing different acidic sites in MOFs is demonstrated and guides proposal and synthesis of new, highly catalytically active MOFs.