Abstract: Metal and oxide clusters protected within small-pore zeolites: synthesis, shape selective properties and inhibition by organosulfur compounds (22nd North American Catalysis Society Meeting)

Monday, June 6, 2011: 5:00 PM

Ambassador Ballroom 2 (Detroit Marriott Hotel at the Renaissance Center )

Zhijie Wu¹, Sarika Goel¹, Minkee Choi² and Enrique Iglesia³, (1)Department of Chemical Engineering, UC Berkeley, Berkeley, CA, (2)Department of Chemical & Biomolecular Engineering, KAIST, Daejeon, South Korea, (3)Department of Chemical Engineering, University of California Berkeley, Berkeley, CA

We report a general synthesis protocol for the selective encapsulation of metal and oxide clusters within small-pore zeolites (LTA, GIS, ANA and SOD) and its consequence for the selection of reactants based on size and for the protection of such clusters against sintering or poisoning by organosulfur and H2S titrants.

Extended Abstracts:

Abstract NACS 2.pdf (143.7KB) - Extended Abstract

See more of: Synthesis and Reactions of Zeolites and Solid Acids (II)
See more of: Catalysis, Materials, and Reaction Engineering for Industrial Chemicals

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OE17 Metal and oxide clusters protected within small-pore zeolites: synthesis, shape selective properties and inhibition by organosulfur compounds