OD08 Highly Regio- and Stereoselective Hydrothiolation of Thiols with Alkynes Catalyzed by Well-Defined Supported Rh-Complex Catalyst

Monday, June 6, 2011: 1:30 PM
Ambassador Ballroom 1 (Detroit Marriott Hotel at the Renaissance Center )
Yong Yang and Robert M. Rioux, Chemical Engineering, Pennsylvania State University, University Park, PA
A robust reusable and well-defined heterogeneous rhodium catalyst for regio- and stereoselective hydrothiolation with high efficiency was developed. The process represents a green methodology for synthesizing vinyl sulfides and extends also the synthetic utility of hydrothiolation reactions.

Extended Abstracts:

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