Structure-Activity Relationship in Ba0.75NiyAl12-YO19-δ Catalysts during CH4 Partial Oxidation

Gardner, Todd

Tuesday, June 16, 2015

Ballroom B (Lawrence Convention Center)

Todd Gardner¹, Edwin L. Kugler^1,2 and James J. Spivey³, (1)National Energy Technology Laboratory, USA, (2)West Virginia University, USA, (3)Louisiana State University, USA.

Ba_0.75Ni_yAl_12-yO_19-δ catalysts with varying levels of Ni loading were characterized and tested for CH₄ partial oxidation. Performance experiments showed stable products with a H₂/CO=2, suitable for FTS. XANES analysis of used catalysts showed a reaction sequence where CH₄ reacted preferentially with O₂ followed by reaction with CO₂ and H₂O.

Extended Abstracts:

HA_abstract2_ 24thNAM_JUN2015.pdf (67.7KB) - Extended Abstract

P-Tu-B-53 Structure-Activity Relationship in Ba0.75NiyAl12-YO19-δ Catalysts during CH4 Partial Oxidation

P-Tu-B-53 Structure-Activity Relationship in Ba_0.75Ni_yAl_12-YO_19-δ Catalysts during CH₄ Partial Oxidation