O-W-A-16 Beyond Ketonization: Selective Conversion of Carboxylic Acids to Olefins over Balanced Lewis Acid-Base Pairs

Wednesday, June 17, 2015: 5:00 PM
Ballroom A (Lawrence Convention Center)
Junming Sun1, Colin Smith2, Rebecca A. L. Baylon1, Changjun Liu1 and Yong Wang2, (1)Washington State University, USA, (2)Pacific Northwest National Laboratory, USA.
we report a highly selective and stable catalyst with balanced Lewis acid-base
pairs, on which mixed carboxylic acids (i.e., acetic acid and propanoic acid) can be selectively
converted into a range of C4-C6 olefins via a sequential ketonization and aldolcondensation
reaction pathway.

Extended Abstracts: