P-Mo-B-84 Long-Range Electron Transfer over Graphene-Based Catalyst for High-Performing Oxygen Reduction Reactions: Importance of Size, N‑Doping, and Metallic Impurities

Monday, June 15, 2015
Ballroom B (Lawrence Convention Center)
Seong Ihl Woo, Korea Advanced Institute of Science and Technology, South Korea.
We show that the first electron is transferred into O2 molecules at the outer Helmholtz plane (ET-OHP) in oxygen reduction reaction. Based on the ET-OHP mechanism, location of the electrode potential dominantly characterizes the ORR activity, and it can be elevated by reducing the graphene size and/or including metal impurities.

Extended Abstracts: