P-Mo-B-26 Design and Synthesis of Supported Single Atom Catalysts through Surface Organometallic Chemistry and Atomic Layer Deposition

Monday, June 15, 2015
Ballroom B (Lawrence Convention Center)
Shengsi Liu1, J. Miles Tan1, Tobin J. Marks1 and Peter C. Stair2, (1)Northwestern University, USA, (2)Argonne National Laboratory, USA.
Atomic palladium species were synthesized by grafting an organometallic palladium complex to SiO2 in solution followed by atomic layer deposition (ALD) of alumina and ozonation. Our work provides an extendable strategy of anchoring single metal atoms to oxide supports with well-defined synthetic steps.

Extended Abstracts: