P-W-B-14 Vapor-Assisted Crystallization Synthesis of Mesoporous (Ti) MIL-125 for Oxidative Desulfurization Applications

Wednesday, June 17, 2015
Ballroom B (Lawrence Convention Center)
Nicholas McNamara and Jason Hicks, University of Notre Dame, USA.
Hierarchical microporous/mesoporous (Ti) MIL-125 was synthesized using a vapor-assisted crystallization method. The hierarchical MIL-125 was examined as an active catalyst for the oxidation of dibenzothiophene with tert-butyl hydroperoxide and outperformed its microporous analogue, which was attributed to greater access of the substrate to surface active sites.

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