P-Mo-B-202 Keto-Hydrodeoxygenation of Acetic Acid to Propylene

Monday, June 15, 2015
Ballroom B (Lawrence Convention Center)
Ayut Witsuthammakul and Tawan Sooknoi, King Mongkut's Institute of Technology Ladkrabang, Thailand.
The upgrading of acetic acid to propylene can be accomplished by the keto-hydrodeoxygenation (KHDO) that integrates ketonization-hydrogenation-dehydration into one-bed catalyst system.  Under H2 stream, propylene and acetone were mainly obtained over tri-functional catalyst (CeO2-5%Cu/HZSM-5 (Si/Al=250)) at 573K. Ethylene and oxygenates are also produced from reduction / hydrogenation of acetic acid.

Extended Abstracts: