P-W-Wil-20 A Novel Reduced Polyoxovanadate Cluster as Oxidative Dehydrogenation Catalyst for Propane

Wednesday, June 5, 2013
Willis (Galt House Hotel)
Kadir Aydemir1, M. Ishaque Khan1, Christopher L. Marshall2 and Robert Doedens3, (1)Illinois Institute of Technology, USA, (2)Argonne National Laboratory, USA, (3)University of California Irvine, USA.
The catalytic properties of a highly reduced polyoxovanadate cluster, (NH4)8[V(IV)13V(V)5O41(OH)(XO4)]10H2O (X = V, S) (NH4V18) towards  the oxidative dehydrogenation (ODH) of propane  was studied. Catalytic performance of both unsupported and γ-alumina supported catalyst was investigated in temperature range of 300-600 oC.

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