How Important is Rh Location on WOX-Ce0.68Zr0.38O2 Supports of Various W Surface Densities in the Autothermal Reforming of n-C10?

Thomas, Cyril

Monday, June 3, 2013

Ballroom C (Galt House Hotel)

Thomas Bonnotte¹, Céline Sayag¹, Rachel P. Doherty¹, Jean-Marc Krafft¹, Christophe Méthivier¹, Frédéric Ser², Mickaël Sicard² and Cyril Thomas³, (1)UPMC, France, (2)ONERA, France, (3)UPMC Laboratoire de Réactivité de Surface, France.

Rh deposited evenly on the oxide phases of WO_x-CZ supports of various W surface densities. N₂-FTIR indicated that the Rh surface atoms were in a zero-valent state on CZ and electron-deficient on WO_x. Rh⁰ sites were estimated to be twice more active in the ATR reaction than the Rh^d⁺ sites.

Extended Abstracts:

4_2013_NACS Louisville_ n-C10 reforming.pdf (19.9KB) - Extended Abstract

P-M-BRC-113 How Important is Rh Location on WOX-Ce0.68Zr0.38O2 Supports of Various W Surface Densities in the Autothermal Reforming of n-C10?

P-M-BRC-113 How Important is Rh Location on WO_X-Ce_0.68Zr_0.38O₂ Supports of Various W Surface Densities in the Autothermal Reforming of n-C₁₀?