OD46 Ligand Stabilization of Noble Metal Complex Catalysts

Wednesday, June 8, 2011: 4:00 PM
Ambassador Ballroom 1 (Detroit Marriott Hotel at the Renaissance Center )
Michael N. Missaghi1, John M. Galloway1, Ivan Konstantinov2, Linda J. Broadbelt2 and Harold H. Kung1, (1)Department of Chemical and Biological Engineering, Northwestern University, Evanston, IL, (2)Chemical and Biological Engineering, Northwestern University, Evanston, IL
Bis(pyridyl)siloxane ligands can effectively stabilize Pd complexes against deactivation by metal agglomeration. The stabilizing effect depends sensitively on the ability of the ligand to form a stable, small monomeric ring complex, suggesting steric protection to be the dominant factor.

Extended Abstracts:

See more of: Selective Oxidation
See more of: Catalysis, Materials, and Reaction Engineering for Industrial Chemicals
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