P-Mo-77 Reversible deactivation of Grubbs metathesis catalysts

Monday, June 6, 2011
Ontario Exhibit Hall (Detroit Marriott Hotel at the Renaissance Center )
Judith Scholz1, Marco Haumann2, Wolfgang Hieringer3 and Peter Wasserscheid1, (1)Chair of Chemical Reaction Engineering, Friedrich-Alexander University of Erlangen-Nürnberg, Erlangen, Germany, (2)Chemical Reaction Engineering, Friedrich-Alexander Universität Erlangen-Nürnberg, Erlangen, Germany, (3)Chair of Theoretical Chemistry, Friedrich-Alexander University of Erlangen-Nürnberg, Erlangen, Germany
Grubbs catalysts were immobilized on silica and tested in gas-phase metathesis reactions. Immobilization was achieved by the application of the Supported Ionic Liquid Phase (SILP) concept. The influence of the alkene feed and product gas on the activity and stability of these catalyst systems was investigated.

Extended Abstracts:

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